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This article explores the concepts of spontaneity and spontaneous order, in particular their deployment by Friedrich Hayek and Karl Polanyi. Although in many respects these thinkers were poles apart, the article identifies a point of convergence. They both mobilize the concept of spontaneity in a manner that naturalizes a particular social process: for Hayek, the market economy, for Polanyi, society’s protective movement that arises in reaction against the market economy. To contextualize the uses of spontaneity by Hayek and Polanyi, I trace its evolution, with reference to Leibniz, Mandeville, and the thinkers of the Scottish Enlightenment. Having sketched the ways in which earlier thinkers understood spontaneity, I turn finally to Hayek and Polanyi. I argue that their invocations of spontaneity and spontaneous order contribute to a downplaying of relations of domination and exploitation. While Hayek sees the market system as the exemplar of spontaneous order, for Polanyi, the concept of spontaneity underpins his belief that the protective countermovement is a ‘natural’ reaction to the evils of market society; as such, power relations pass beneath the radar.